The reaction mechanism for the formation of alkyl thiol SAM on Au(111) is still not.
thiols (with long and short chains and di-thiol species) adsorbed on gold.
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However, chemical reaction conditions optimized for Au(I)–thiolate.
By considering the four isomers of butanethiol (14), we have shown that.
In this process, gold atoms on the nanoparticles' surface react with the thiol, dissolving as gold-thiolate complexes until the dissolution reaction stops; this leaves.
thiol molecules bound to gold surfaces. Kelvin force.
stirrer. To this, was added NaSC2H5 (5.5 g; 0.0647 mol), and the reaction mixture was refluxed under N2,